Journal of Automotive Safety and Energy ›› 2021, Vol. 12 ›› Issue (4): 417-439.DOI: 10.3969/j.issn.1674-8484.2021.04.001
• Review, Progress and Prospects • Next Articles
SHUAI Shijin1(
), WANG Zhi1, MA Xiao1, XU Hongming2, HE Xin3, WANG Jianxin1
Received:2021-12-07
Online:2021-12-31
Published:2022-01-10
CLC Number:
SHUAI Shijin, WANG Zhi, MA Xiao, XU Hongming, HE Xin, WANG Jianxin. Low carbon and zero carbon technology paths and key technologies of ICEs under the background of carbon neutrality[J]. Journal of Automotive Safety and Energy, 2021, 12(4): 417-439.
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URL: https://www.journalase.com/EN/10.3969/j.issn.1674-8484.2021.04.001
| 温室气体排放 | 平均温升控制在 2.0 ℃以内 | 平均温升控制在 1.5 ℃以内 | ||||
|---|---|---|---|---|---|---|
| 2020 | 2030 | 2050 | 2020 | 2030 | 2050 | |
| 能源消费CO2 排放 | 100.3 | 104.6 | 29.2 | 100.3 | 104.5 | 14.7 |
| 工业过程CO2 排放 | 13.2 | 11.0 | 4.7 | 13.2 | 8.8 | 2.5 |
| 非CO2温室气体排放 | 24.4 | 27.8 | 17.6 | 24.4 | 26.5 | 12.7 |
| 森林碳汇 | -5.8 | -6.1 | -7.0 | -7.2 | -9.1 | -7.8 |
| 碳捕集(CCS) | 0.0 | 0.0 | -5.1 | 0.0 | -0.3 | -8.8 |
| 净排放 | 132.1 | 137.3 | 39.4 | 130.7 | 130.4 | 13.3 |
| 温室气体排放 | 平均温升控制在 2.0 ℃以内 | 平均温升控制在 1.5 ℃以内 | ||||
|---|---|---|---|---|---|---|
| 2020 | 2030 | 2050 | 2020 | 2030 | 2050 | |
| 能源消费CO2 排放 | 100.3 | 104.6 | 29.2 | 100.3 | 104.5 | 14.7 |
| 工业过程CO2 排放 | 13.2 | 11.0 | 4.7 | 13.2 | 8.8 | 2.5 |
| 非CO2温室气体排放 | 24.4 | 27.8 | 17.6 | 24.4 | 26.5 | 12.7 |
| 森林碳汇 | -5.8 | -6.1 | -7.0 | -7.2 | -9.1 | -7.8 |
| 碳捕集(CCS) | 0.0 | 0.0 | -5.1 | 0.0 | -0.3 | -8.8 |
| 净排放 | 132.1 | 137.3 | 39.4 | 130.7 | 130.4 | 13.3 |
| 沸点 | -252.77 ℃ | 熔点 | -259.2 ℃ |
|---|---|---|---|
| 密度 | 0.089 g/L | 气液容积比(15 ℃,100 kPa) | 974 L/L |
| 相对分子质量 | 2.0157 | 临界密度 | 66.8 kg/m3 |
| 生产方法 | 电解水、裂解、煤制气等 | 临界压力 | 1.313 MPa |
| 三相点 | -254.4 ℃ | 燃烧界限(空气中的氢气体积) | 4%~75% |
| 熔化热(-254.5℃,平衡态) | 48.84 kJ/kg | 表面张力(平衡态,-252.8 ℃) | 3.72 mN/m |
| 热值(2.82×105 J/mol) | 1.4×108 J/kg | 折射系数(101.3 kPa,25℃) | 1.000 126 5 |
| 比热比(101.3 kPa,25℃,气体) | cp / cV = 1.40 | 易燃性级别 | 4级 |
| 易爆性级别 | 1级 | 毒性级别 | 0级 |
| 沸点 | -252.77 ℃ | 熔点 | -259.2 ℃ |
|---|---|---|---|
| 密度 | 0.089 g/L | 气液容积比(15 ℃,100 kPa) | 974 L/L |
| 相对分子质量 | 2.0157 | 临界密度 | 66.8 kg/m3 |
| 生产方法 | 电解水、裂解、煤制气等 | 临界压力 | 1.313 MPa |
| 三相点 | -254.4 ℃ | 燃烧界限(空气中的氢气体积) | 4%~75% |
| 熔化热(-254.5℃,平衡态) | 48.84 kJ/kg | 表面张力(平衡态,-252.8 ℃) | 3.72 mN/m |
| 热值(2.82×105 J/mol) | 1.4×108 J/kg | 折射系数(101.3 kPa,25℃) | 1.000 126 5 |
| 比热比(101.3 kPa,25℃,气体) | cp / cV = 1.40 | 易燃性级别 | 4级 |
| 易爆性级别 | 1级 | 毒性级别 | 0级 |
| AEL 法 | PEMEL法 | SOEC法 | |
|---|---|---|---|
| 电解原料 | KOH/NaOH溶液 | 纯水 | 水蒸气 |
| 电解温度 / ℃ | 80~90 | 90~120 | 600~900 |
| 电极面积 / m2 | < 3 | < 0.2 | — |
| 电流密度 /(kA·cm-2) | 2.0~5.5 | 10.0~30.0 | 2.0~6.0 |
| 电解电压 / V | 1.75~2.10 | 1.72~2.20 | 约1.50 |
| 耗电参数 / (kWh·m-3) | 4.5~6.5 | 4.8~6.0 | 3.5~4.5 |
| 装置价格 / (万元·m-3h-1) | 80 | 150 | — |
| 规模 / (m3·h-1) | > 500 | 50 | > 5 000 |
| AEL 法 | PEMEL法 | SOEC法 | |
|---|---|---|---|
| 电解原料 | KOH/NaOH溶液 | 纯水 | 水蒸气 |
| 电解温度 / ℃ | 80~90 | 90~120 | 600~900 |
| 电极面积 / m2 | < 3 | < 0.2 | — |
| 电流密度 /(kA·cm-2) | 2.0~5.5 | 10.0~30.0 | 2.0~6.0 |
| 电解电压 / V | 1.75~2.10 | 1.72~2.20 | 约1.50 |
| 耗电参数 / (kWh·m-3) | 4.5~6.5 | 4.8~6.0 | 3.5~4.5 |
| 装置价格 / (万元·m-3h-1) | 80 | 150 | — |
| 规模 / (m3·h-1) | > 500 | 50 | > 5 000 |
| 含氢质量分数 % | 沸点 ℃ | 质量热值 MJ·kg-1 | 混合气热值MJ·kg-1 | 层流火焰速度 m·s-1 | 最小点火能量 mJ | 可燃极限体积 % | 辛烷值 RON | |
|---|---|---|---|---|---|---|---|---|
| 氨 | 17.7 | -33.4 | 18.6 | 2.61 | 0.07 | 680 | 15~28 | 130 |
| 氢 | 100.0 | -253.0 | 120.0 | 3.62 | 1.60 | 0.011 | 4~75 | ≥ 100, 130 |
| 柴油 | 12.6 | 180~360 | 42.5 | 2.78 | 15~25 | |||
| 汽油 | 14.5 | 20~215 | 44.0 | 2.80 | 0.34 | 0.8 | 90~106 | |
| 甲醇 | 12.5 | 64.7 | 23.9 | 3.18 | 0.40 | 0.14 | 6.7~36.0 | 108 |
| 乙醇 | 13.0 | 78.0 | 29.7 | 2.95 | 0.40 | 3.2~18.8 | 108 | |
| 二甲醚 | 13.0 | -29.5 | 31.8 | 3.15 | 0.43 | 0.29 | 3.4~27.0 | 0 |
| 含氢质量分数 % | 沸点 ℃ | 质量热值 MJ·kg-1 | 混合气热值MJ·kg-1 | 层流火焰速度 m·s-1 | 最小点火能量 mJ | 可燃极限体积 % | 辛烷值 RON | |
|---|---|---|---|---|---|---|---|---|
| 氨 | 17.7 | -33.4 | 18.6 | 2.61 | 0.07 | 680 | 15~28 | 130 |
| 氢 | 100.0 | -253.0 | 120.0 | 3.62 | 1.60 | 0.011 | 4~75 | ≥ 100, 130 |
| 柴油 | 12.6 | 180~360 | 42.5 | 2.78 | 15~25 | |||
| 汽油 | 14.5 | 20~215 | 44.0 | 2.80 | 0.34 | 0.8 | 90~106 | |
| 甲醇 | 12.5 | 64.7 | 23.9 | 3.18 | 0.40 | 0.14 | 6.7~36.0 | 108 |
| 乙醇 | 13.0 | 78.0 | 29.7 | 2.95 | 0.40 | 3.2~18.8 | 108 | |
| 二甲醚 | 13.0 | -29.5 | 31.8 | 3.15 | 0.43 | 0.29 | 3.4~27.0 | 0 |
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