汽车安全与节能学报 ›› 2023, Vol. 14 ›› Issue (5): 521-535.DOI: 10.3969/j.issn.1674-8484.2023.05.001
• 综述与展望 • 下一篇
收稿日期:
2023-09-11
修回日期:
2023-09-19
出版日期:
2023-10-31
发布日期:
2023-10-31
通讯作者:
*姚安仁,工学博士。E-mail:作者简介:
姚春德 教授,天津大学教授,现任工信部甲醇汽车推广应用专家委员会副主任。长期从事内燃机燃烧学、内燃机替代燃料及其排放的基础理论与应用研究,在甲醇燃料的着火和燃烧及其应用、爆震燃烧发生机理及其控制等领域具有深厚的研究基础和造诣。2015年获得中国机械工业联合会科技发明一等奖,2017年获得教育部技术发明二等奖。
基金资助:
Received:
2023-09-11
Revised:
2023-09-19
Online:
2023-10-31
Published:
2023-10-31
Contact:
*Dr. YAO Anren,A dedicated researcher in the School of Environmental Science and Engineering in Tianjin University. His study focuses on the metallic material and methanol practical application and the theories to internal combustion engines. He has plentiful experiences on making methanol fuel to be applied to various types of compression ignition engines. He has honored with the First-Rate Award from China Machinery Industry Federation in 2015 and the Second-Rate Award from China Ministry of Education in 2017.
About author:
Prof. YAO Chunde,A professor in Tianjin University, the vice director of Experts Committee for Methanol Application and Promotion of Ministry of Industry and Information Technology (MIIT). He focuses his study on the working process of internal combustion engines and its alternative fuel as well as exhaust emission control, especially in methanol mixture ignition and burning, knocking combustion and control. He has honored with the First-Rate Award from China Machinery Industry Federation in 2015 and the Second-Rate Award from China Ministry of Education in 2017.
摘要:
甲醇的物性与汽油、柴油相近,常温、常压下是液体,生产资料丰富,方便储存、运输和加注。绿色甲醇已经被国际航运界公认为低碳和碳中和的燃料,在船舶动力上应用日益增长。中国是具有全球最大甲醇产能以及最大产量的国家,产能和产量都占全球近60%。甲醇生产不仅可用煤炭和天然气做原料,更具有用可再生电力制氢,然后与二氧化碳合成绿色甲醇的能力。中国对甲醇用作替代石油燃料的研发工作由来已久,不仅在工农业领域得到大量应用,而且也大量应用在交通运输领域。自20世纪70年代以来开展的甲醇在内燃机上替代汽油、柴油研究,目前已经在应用技术上取得根本突破。不仅在乘用车、商用车得到规模应用,也在工程机械、内燃机车和中高速船舶动力应用上取得突破,实现甲醇应用技术完全独立自主。该综述简要介绍甲醇的生产、对甲醇毒性的认识、绿色甲醇的发展、甲醇在工农业和交通领域方面的应用概况,重点介绍在车辆、船舶、内燃机车、发电机组的汽油机和柴油机上应用甲醇的技术特点,指出其发展存在问题并展望甲醇应用的未来。
中图分类号:
姚春德, 姚安仁. 甲醇燃料的应用现状及其展望[J]. 汽车安全与节能学报, 2023, 14(5): 521-535.
YAO Chunde, YAO Anren. Review on methanol as fuel for engines and its future prospect[J]. Journal of Automotive Safety and Energy, 2023, 14(5): 521-535.
性质/单位 | 甲醇 | 汽油 | 柴油 |
---|---|---|---|
化学式 | CH3OH | C4~C14的烃类化合物 | C16~C23的烃类化合物 |
相对分子质量 | 32.04 | 95~120 | 180~200 |
C/H原子量比 | 3.0 | 5.6~7.4 | 6.4~7.2 |
密度(20oC) /(kg·L-1) | 0.792 | 0.72~0.78 | 0.82~0.86 |
冰点/ oC | -96 | -57 | -1~-4 |
沸点/ oC | 64.7 | 27~225 | 180~370 |
闪点/ oC | 12 | 45 | 75 |
自燃温度/ oC | 450 | 350~468 | 260~350 |
汽化潜热/(kJ·kg-1) | 1 167 | 310 | 270 |
着火界限(体积分数) / % | 6.7~36.5 | 1.4~6.7 | 1.5~8.2 |
低热值/(kJ·kg-1) | 19 930 | 43 030 | 42 500 |
辛烷值(RON) | 114.4 | 89~98 | — |
十六烷值 | 3 | 0~10 | 45~55 |
理论空燃比(空气与燃料质量比) /(kg·kg-1) | 6.5 | 14.8 | 14.6 |
性质/单位 | 甲醇 | 汽油 | 柴油 |
---|---|---|---|
化学式 | CH3OH | C4~C14的烃类化合物 | C16~C23的烃类化合物 |
相对分子质量 | 32.04 | 95~120 | 180~200 |
C/H原子量比 | 3.0 | 5.6~7.4 | 6.4~7.2 |
密度(20oC) /(kg·L-1) | 0.792 | 0.72~0.78 | 0.82~0.86 |
冰点/ oC | -96 | -57 | -1~-4 |
沸点/ oC | 64.7 | 27~225 | 180~370 |
闪点/ oC | 12 | 45 | 75 |
自燃温度/ oC | 450 | 350~468 | 260~350 |
汽化潜热/(kJ·kg-1) | 1 167 | 310 | 270 |
着火界限(体积分数) / % | 6.7~36.5 | 1.4~6.7 | 1.5~8.2 |
低热值/(kJ·kg-1) | 19 930 | 43 030 | 42 500 |
辛烷值(RON) | 114.4 | 89~98 | — |
十六烷值 | 3 | 0~10 | 45~55 |
理论空燃比(空气与燃料质量比) /(kg·kg-1) | 6.5 | 14.8 | 14.6 |
排放浓度/ [g·(kWh)-1] | BTE % | |||||
---|---|---|---|---|---|---|
NOx | PM | CO | THC | BSFC | ||
国VI限值 | 0.40 | 10.00 | 1.50 | 0.13 | — | — |
原机 | 11.35 | 6.20 | 0.48 | 0.21 | — | — |
原机 + DOC + CDPF | 10.64 | 0.40 | 0.05 | 0.14 | 222.5 | 38.1 |
DMCC | 0.38 | 35.02 | 10.60 | 3.50 | — | — |
DMCC + DOC + CDPF | 0.36 | 7.66 | 0.04 | 0.35 | 214.6 | 39.5 |
排放浓度/ [g·(kWh)-1] | BTE % | |||||
---|---|---|---|---|---|---|
NOx | PM | CO | THC | BSFC | ||
国VI限值 | 0.40 | 10.00 | 1.50 | 0.13 | — | — |
原机 | 11.35 | 6.20 | 0.48 | 0.21 | — | — |
原机 + DOC + CDPF | 10.64 | 0.40 | 0.05 | 0.14 | 222.5 | 38.1 |
DMCC | 0.38 | 35.02 | 10.60 | 3.50 | — | — |
DMCC + DOC + CDPF | 0.36 | 7.66 | 0.04 | 0.35 | 214.6 | 39.5 |
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