汽车安全与节能学报 ›› 2022, Vol. 13 ›› Issue (1): 1-28.DOI: 10.3969/j.issn.1674-8484.2022.01.001
• 综述与展望 • 下一篇
章俊良1,2,*(), 程明1(), 罗夏爽1, 李慧媛1, 罗柳轩1, 程晓静1, 闫晓晖1(), 沈水云1,2()
收稿日期:
2022-03-23
修回日期:
2022-03-26
出版日期:
2022-03-31
发布日期:
2022-04-02
通讯作者:
章俊良,闫晓晖,沈水云
作者简介:
基金资助:
ZHANG Junliang1,2,*(), CHENG Ming1(), LUO Xiashuang1, LI Huiyuan1, LUO Liuxuan1, CHENG Xiaojing1, YAN Xiaohui1(), SHEN Shuiyun1,2()
Received:
2022-03-23
Revised:
2022-03-26
Online:
2022-03-31
Published:
2022-04-02
Contact:
ZHANG Junliang,YAN Xiaohui,SHEN Shuiyun
摘要:
“双碳”政策大大推动了氢能的发展,而燃料电池作为氢能利用的最佳方式,迎来了新一轮的研究与产业热潮,尤其是商业化较为成熟的车用质子交换膜燃料电池(PEMFC)引发了众多关注。膜电极(MEA)和双极板(BPP)是PEMFC电堆的两大核心部件,决定了电堆的性能和成本。水热管理和低温启动技术对于电堆性能的实现和实际应用的推广也起到了至关重要的作用。本文全面深入地阐述了车用PEMFC膜电极、双极板、水热管理、低温启动等技术对电堆性能、寿命和成本的影响规律,进一步指出各项技术的发展趋势。除此之外,车用燃料电池的商业化应用短期将围绕公共交通以及重型商用车等大型车辆开展,而乘用车对电堆的功率密度和成本提出了更高的要求。
中图分类号:
章俊良, 程明, 罗夏爽, 李慧媛, 罗柳轩, 程晓静, 闫晓晖, 沈水云. 车用燃料电池电堆关键技术研究现状[J]. 汽车安全与节能学报, 2022, 13(1): 1-28.
ZHANG Junliang, CHENG Ming, LUO Xiashuang, LI Huiyuan, LUO Liuxuan, CHENG Xiaojing, YAN Xiaohui, SHEN Shuiyun. Current status of the research on key technologies of vehicle fuel cell stack[J]. Journal of Automotive Safety and Energy, 2022, 13(1): 1-28.
厂商 | 国鸿氢能 | 新源动力 | 神力科技 | Ballard | Toyota | DOE2025目标 |
---|---|---|---|---|---|---|
代表型号 | 鸿芯GI | HYMOD-150 | SFC-B9P | FCgen-HPS | Mirai2 | ? |
发布年份 | 2020 | 2021 | 2021 | 2020 | 2020 | ? |
电堆类型 | 柔性石墨 | 金属 | 模压石墨 | 柔性石墨 | 金属 | ? |
电堆功率 / kW | 84 | 150 | 150 | 140 | 128 | ? |
质量功率密度 / (kW∙kg-1) | 2.4 | ? | ? | 4.7 | 5.4 | 2.7 |
体积功率密度 / (kW·L-1) | 3.8 | 4.5 | 4.0 | 4.3 | 5.4 | ? |
能量效率 / % | ? | ? | ? | 52 | ? | 65 |
无辅助冷启动温度 / ℃ | ?30 | ? | ?35 | ?28 | ?30 | ?30 |
Pt载量 / (g∙kW-1) | <0.25 | ? | ? | ? | 0.11 | 0.1 |
寿命 / h | > 20 000 | 10 000 | > 15 000 | > 20 000 | > 5 000 | 8 000 |
成本 | 1 199 CNY/kW | ? | ? | ? | < 200 USD/kW | 17.5 USD/kW |
产能 / (kW∙a-1) | 0.5 M | ? | ? | ? | 1.28 M | 40 M |
厂商 | 国鸿氢能 | 新源动力 | 神力科技 | Ballard | Toyota | DOE2025目标 |
---|---|---|---|---|---|---|
代表型号 | 鸿芯GI | HYMOD-150 | SFC-B9P | FCgen-HPS | Mirai2 | ? |
发布年份 | 2020 | 2021 | 2021 | 2020 | 2020 | ? |
电堆类型 | 柔性石墨 | 金属 | 模压石墨 | 柔性石墨 | 金属 | ? |
电堆功率 / kW | 84 | 150 | 150 | 140 | 128 | ? |
质量功率密度 / (kW∙kg-1) | 2.4 | ? | ? | 4.7 | 5.4 | 2.7 |
体积功率密度 / (kW·L-1) | 3.8 | 4.5 | 4.0 | 4.3 | 5.4 | ? |
能量效率 / % | ? | ? | ? | 52 | ? | 65 |
无辅助冷启动温度 / ℃ | ?30 | ? | ?35 | ?28 | ?30 | ?30 |
Pt载量 / (g∙kW-1) | <0.25 | ? | ? | ? | 0.11 | 0.1 |
寿命 / h | > 20 000 | 10 000 | > 15 000 | > 20 000 | > 5 000 | 8 000 |
成本 | 1 199 CNY/kW | ? | ? | ? | < 200 USD/kW | 17.5 USD/kW |
产能 / (kW∙a-1) | 0.5 M | ? | ? | ? | 1.28 M | 40 M |
厂商 | 东岳未来 | 科润新材料 | Chemours | DOE2025目标 |
---|---|---|---|---|
代表型号 | DF260 | N-3010 | NC700 | ? |
发布年份 | 2017 | ? | 2019 | ? |
厚度 / μm | 15 | 10 | 15 | ? |
电导率 / (mS∙cm-1) | 60 (80 ℃, 50% RH) | 95 (80 ℃, 90% RH) | ? | ? |
面比电阻 | ? | ? | < 20 mΩ∙cm2 | 20 mΩ∙cm2 |
模量/ MPa | 350 (TD), 350 (MD) | 400 (TD), 480 (MD) | 421 (TD), 446 (MD) | ? |
拉伸强度 / MPa | 14 (TD), 15 (MD) | 38 (TD), 45 (MD) | 45 (TD), 45 (MD) | ? |
断裂伸长率 / % | 120 (TD), 100 (MD) | 150 (TD), 175 (MD) | 61 (TD), 105 (MD) | ? |
溶胀率 / % | 2 (TD), 5 (MD) | 4 (TD), 5 (MD) | 4 (TD), 4 (MD) | ? |
最高温度 | ? | ? | ? | 120 ℃ |
渗氢电流 | 11 mA/cm2 | < 2 mA/cm2 | ? | 2 mA/cm2 |
干-湿机械 耐久性 | 22 000 次 循环 | ? | ? | 20 000 次 循环 |
OCV化学 耐久性 | 600 h | ? | ? | 500 h |
验证寿命 | 6 000 h | ? | ? | ? |
成本 | ? | ? | ? | 17.5 USD/m2 |
产能 / (104 m2·a-1) | 150 | 100 | ? | ? |
厂商 | 东岳未来 | 科润新材料 | Chemours | DOE2025目标 |
---|---|---|---|---|
代表型号 | DF260 | N-3010 | NC700 | ? |
发布年份 | 2017 | ? | 2019 | ? |
厚度 / μm | 15 | 10 | 15 | ? |
电导率 / (mS∙cm-1) | 60 (80 ℃, 50% RH) | 95 (80 ℃, 90% RH) | ? | ? |
面比电阻 | ? | ? | < 20 mΩ∙cm2 | 20 mΩ∙cm2 |
模量/ MPa | 350 (TD), 350 (MD) | 400 (TD), 480 (MD) | 421 (TD), 446 (MD) | ? |
拉伸强度 / MPa | 14 (TD), 15 (MD) | 38 (TD), 45 (MD) | 45 (TD), 45 (MD) | ? |
断裂伸长率 / % | 120 (TD), 100 (MD) | 150 (TD), 175 (MD) | 61 (TD), 105 (MD) | ? |
溶胀率 / % | 2 (TD), 5 (MD) | 4 (TD), 5 (MD) | 4 (TD), 4 (MD) | ? |
最高温度 | ? | ? | ? | 120 ℃ |
渗氢电流 | 11 mA/cm2 | < 2 mA/cm2 | ? | 2 mA/cm2 |
干-湿机械 耐久性 | 22 000 次 循环 | ? | ? | 20 000 次 循环 |
OCV化学 耐久性 | 600 h | ? | ? | 500 h |
验证寿命 | 6 000 h | ? | ? | ? |
成本 | ? | ? | ? | 17.5 USD/m2 |
产能 / (104 m2·a-1) | 150 | 100 | ? | ? |
厂商 | 上海弘枫 | 喜马拉雅 | 上海治臻 | DOE2025目标 |
---|---|---|---|---|
极板类型 | 超薄石墨 | 石墨复合模压 | SS316L/Ti合金 | ? |
板材重量 / (kg∙kW-1) | ? | ? | ? | 0.18 |
渗氢系数 (@80 ℃ 3 atm 100% RH) / [cm3∙(s∙cm2∙Pa)-1] | ? | ? | ? | < 1.3×10-14 |
厚度/ mm | 1.4 | 0.3 (最小处) | 1.1 | ? |
电导率/ (S∙cm-1) | > 800 | > 625 | ? | > 100 |
热导率/ [W∙(m∙K)-1] | ? | ? | ? | > 20 |
抗弯强度 / MPa | > 50 | > 51 | ? | > 40 |
接触电阻 / (mΩ∙cm-2) | < 6.5 | ? | 2 | < 10 (@1.4 MPa) |
腐蚀电流 / (μA∙cm-2) | ? | ? | < 0.5 | < 1 |
成型伸长率 / % | ? | ? | ? | 40 |
验证寿 / h | ? | > 10 000 | > 5 000 | ? |
成本 | ? | ? | ? | 2 $/ kW |
产能 / (104片∙a-1) | > 400 | ? | 340 | ? |
厂商 | 上海弘枫 | 喜马拉雅 | 上海治臻 | DOE2025目标 |
---|---|---|---|---|
极板类型 | 超薄石墨 | 石墨复合模压 | SS316L/Ti合金 | ? |
板材重量 / (kg∙kW-1) | ? | ? | ? | 0.18 |
渗氢系数 (@80 ℃ 3 atm 100% RH) / [cm3∙(s∙cm2∙Pa)-1] | ? | ? | ? | < 1.3×10-14 |
厚度/ mm | 1.4 | 0.3 (最小处) | 1.1 | ? |
电导率/ (S∙cm-1) | > 800 | > 625 | ? | > 100 |
热导率/ [W∙(m∙K)-1] | ? | ? | ? | > 20 |
抗弯强度 / MPa | > 50 | > 51 | ? | > 40 |
接触电阻 / (mΩ∙cm-2) | < 6.5 | ? | 2 | < 10 (@1.4 MPa) |
腐蚀电流 / (μA∙cm-2) | ? | ? | < 0.5 | < 1 |
成型伸长率 / % | ? | ? | ? | 40 |
验证寿 / h | ? | > 10 000 | > 5 000 | ? |
成本 | ? | ? | ? | 2 $/ kW |
产能 / (104片∙a-1) | > 400 | ? | 340 | ? |
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